phase equilibrium


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In general, to calculate the CO2 absorbed by amine solution, the gas/liquid-phase mass transfer coefficients, the effective interfacial area, the enhancement factor, and the phase equilibrium of the system are required [21,27,28]. The phase equilibrium of CO2 and aqueous solvent sys- tem are also essential to calculate the mass transfer rate along the column height. The Henry constant method and more rigorous methods such as the Electrolyte Nonrandom Two-liquid (e-NRTL) activity coefficient model and Universal Quasi Chemical (UNIQUAC) activity coefficient model have been used to retrieve the phase equilibrium of the system [28,36,37]. The phase equilibrium is required to determine the liquid phase driving force and solution speciation [36,38,39]. Phase equilibrium

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